Would you consider a 225 on a 7" wide rim as stuffed
Not at all. Earluy S2k's have a 6.5" wheel that I run 225's on....not stretched at all. Wider is better!
A 225 would work on a 7" rim (that's what I'm running on the front end of my car), but I would consider it slightly "stuffed".
I wouldn't say wider is better either. Two years ago I tested both 245 and 275 Rivals on the 8" front wheels of my then car, a BMW M3. Much to my surprise, there was no discernible difference in either feel or times. Another M3 driver, thinking I was crazy, repeated the same experiment on his car with the same result.
Last year I tested both 255s and 275 RE-71Rs on the 8.5" front wheels of my Corvette, and again the results were inconclusive. Many other national-level drivers did the same test on their Corvettes -- some found the 275s to be faster, some found no difference, and one found the 255s to be much faster.
This year I tested 225s and 195s on the 7" rear wheels of my Mini, and was flabbergasted to again notice no discernible difference.
This is all a long-winded way of saying that I don't think you're going to notice a significant balance change from putting 225s on your rear wheels. Putting that much tire on a 7" wheel is definitely into the range of diminishing returns, and potentially in the zone of no benefit at all. (I'm going to test 205s on the front end of my car next.)
I wonder if 225 ZII's would be gripper than 205 RE71R's
No. Rubber compound trumps width.